In a large skillet over medium heat, heat olive oil. Season both sides of pork chops with salt and pepper. Add pork chops to the skillet in a single layer and cook until golden on both sides, 2 to 3 minutes per side.
Meanwhile, make crack sauce: In a medium bowl, whisk together barbecue sauce, brown sugar, lime juice, and garlic powder.
When the pork chops are golden, add the crack sauce to the pan and bring sauce to a boil. Reduce heat to medium, cover the skillet with a tight-fitting lid, and simmer until the pork is cooked through, 4 to 5 minutes more.